The provenance of slovenian milk using ⁸⁷Sr/⁸⁶Sr isotope ratios.

This work presents the first use of Sr isotope ratios for determining the provenance of bovine milk from different regions of Slovenia. The analytical protocol for the determination of ⁸⁷Sr/⁸⁶Sr isotope ratio was optimised and applied to authentic milk samples. Considerable variability of ⁸⁷Sr/⁸⁶Sr ratios found in Slovenian milk reflects the substantial heterogeneity of the geological background of its origin. The results, although promising, cannot discount possible inter-annual or annual variation of the Sr isotopic composition of milk. The ⁸⁷Sr/⁸⁶Sr ratios of groundwater and surface waters are in good correlation with milk, indicating that the Sr isotopic fingerprint in milk is reflective of cow drinking water. The ⁸⁷Sr/⁸⁶Sr ratio has the potential to distinguish between different milk production areas as long as these areas are characterised by geo-lithology. Discriminant analysis (DA) incorporating the elemental composition and stable isotopes...